منابع مشابه
Mechanism and Site Requirements of Thiophene Hydrodesulfurization Catalyzed by Supported Pt Clusters
Hydrodesulfurization (HDS) processes remove sulfur atoms from hydrocarbons by chemical reduction to hydrogen sulfide using H2 with transition metals and their sulfides as catalysts. Mechanistic and structural insights, concerning reaction pathways and catalysts, respectively, are required to design more effective HDS catalysts, with higher rates at lower H2 pressures, so as to meet emerging req...
متن کاملThiophene hydrodesulfurization catalysis on supported Ru clusters: Mechanism and site requirements for hydrogenation and desulfurization pathways
Kinetic and isotopic methods were used to probe elementary steps and site requirements for thiophene hydrogenation and desulfurization on Ru metal clusters. Turnover rates for these reactions were unaffected by whether samples were treated in H2 or H2S to form metal and sulfide clusters, respectively, before reaction. These data, taken together with the rate and extent of sulfur removal from us...
متن کاملSurface science models for CoMo hydrodesulfurization catalysts: Influence of the support on hydrodesulfurization activity
• A submitted manuscript is the author's version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website. • The final author version ...
متن کاملSonochemical preparation of supported hydrodesulfurization catalysts.
Sonochemical preparation of Co and Ni promoted MoS(2) supported on alumina was achieved by high-intensity ultrasonic irradiation of isodurene solutions containing molybdenum carbonyl, dicobalt octacarbonyl, elemental sulfur, and Al(2)O(3) or Ni-Al(2)O(3) under Ar flow. The sonochemically prepared catalysts were characterized by elemental analysis, XPS, SEM, TEM, and XEDS, and hydrodesulfurizati...
متن کاملMolecular Modeling of Gas Oil Hydrodesulfurization
The hydrodesulfurization (HDS) process chemistry and reaction network have been modeled at the molecular level. The following sulfur compound types have been considered: mercaptans, sulfides, disulfides, thiophenes (T), benzothiophenes (BT), dibenzothiophenes (DBT), and their alkyl and hydrogenated derivatives. The steric and electronic effects of the alkyl side chain of thiophenic compounds (T...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1971
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.74.7_1317